The main difference between a water bath and oil bath for a rotary evaporator (rotavap) lies in the type of heating medium used to heat the sample flask.

Differences between the two types of baths:
- Heating medium: Water baths use water as the heating medium, while oil baths use oil. Water is a common and inexpensive heating medium that is readily available, while oil is a more expensive but more stable and efficient heating medium.
- Temperature range: Water baths typically have a lower maximum temperature range than oil baths, with a maximum temperature of around 100°C. Oil baths can reach higher temperatures, with a maximum temperature range of up to 250°C or higher.
- Stability: Oil baths are generally more stable than water baths, as oil has a higher heat capacity and can maintain a more stable temperature. Water baths can experience temperature fluctuations due to changes in ambient temperature or the addition of cool water or samples.
- Evaporation rate: The type of heating medium used can also affect the evaporation rate of the solvent. Oil baths can heat the sample flask more evenly and efficiently, resulting in faster evaporation rates than water baths.
- Safety: Water baths are generally considered safer than oil baths, as water is non-flammable and does not present a risk of fire or explosion. Oil baths can present a fire hazard if the oil is heated too high or if it comes into contact with a spark or other ignition source.
- Maintenance: Water baths are generally easier to maintain than oil baths, as they do not require oil changes or the use of additives. Oil baths require regular oil changes and the use of additives to maintain their stability and efficiency.
Overall, the choice between a water bath and oil bath for a rotary evaporator depends on the specific application and the desired temperature range and heating efficiency. Water baths are a good choice for applications that require lower temperatures and a safer heating medium, while oil baths may be necessary for high-temperature applications or for more stable and efficient heating. It is important to follow proper safety protocols when using either type of bath to ensure safe and effective operation of the rotary evaporator.